1. Catalytic Enantioselective Desymmetrization of Meso Cyclic Anhydrides via Iridium-Catalyzed Hydrogenation. Liu, T. L.; Li, W.; Geng, H. L.; Wang, C. J.; Zhang, X. M. Organic Letters. 2013, 15, 1740.
2. Rhodium-Catalyzed Asymmetric Hydroformylation of 1,1-Disubstituted Allylphthalimides: A Catalytic Route to β3-Amino Acids. Zheng, X.; Cao, B. N.; Liu, T. L.; Zhang, X. M. Advanced Synthesis & Catalysis. 2013, 355, 679.
3. Cascade Synthesis of Fenpiprane and Related Pharmaceuticals via Rhodium-Catalyzed Hydroaminomethylation. Li, S. K.; Huang, K. X.; Zhang, J. W.; Wu, W. J.; Zhang, X. M. Organic Letters. 2013, 15, 1036.
4. A Novel Triphosphoramidite Ligand for Highly Regioselective Linear Hydroformylation of Terminal and Internal Olefins Chen, C. Y.; Qiao, Y.; Geng, H. L.; Zhang, X. M. Organic Letters. 2013, 15, 1048.
5. Rhodium-Catalyzed Enantioselective Hydrogenation of Oxime Acetates.Huang, K. X.; Li, S. K.; Chang, M. X.; Zhang, X. M. Organic Letters. 2013, 15, 484.
6. Highly enantioselective hydrogenation of β,β-disubstituted nitroalkenes. Li, Shengkun; Huang, Kexuan; Cao, Bonan; Zhang, Jiwen; Wu, Wenjun; Zhang, Xumu. Angew. Chem. Int. Edit. 2012, 51, 10679. DOI: 10.1002/anie.201202715
7. New tetraphosphorus ligands for highly linear selective hydroformylation of allyl and vinyl derivatives. Cai, Chaoxian; Yu, Shichao; Cao, Bonan; Zhang, Xumu. Chem. Eur. J. 2012, 18, DOI: 10.1002/chem.201201396.
8. Access to both enantiomers of α-chloro-β-keto esters with a single chiral ligand: highly efficient enantioselective chlorination of cyclic β-keto esters catalyzed by chiral copper(II) and zinc(II) complexes of a spiro-2,2'-bischroman-based bisoxazoline ligand. Li, Jie; Pan, Wei; Wang, Zheng; Zhang, Xumu; Ding, Kuiling. Adv. Synth. Catal. 2012, 354, 1980.
9. Highly enantioselective hydrogenation of β-ketoenamides with the Rh-ZhangPhos catalyst. Huang, Kexuan; Zhang, Xiaowei; Geng, Huiling; Li, Sheng-kun; Zhang, Xumu. ACS Catalysis 2012, 2, 1343.
10. Highly regioselective isomerization-hydroaminomethylation of internal olefins catalyzed by Rh complex with Tetrabi-type phosphorus ligands. Liu, Guodu; Huang, Kexuan; Cao, Bonan; Chang, Mingxin; Li, Shengkun; Yu, Shichao; Zhou, Le; Wu, Wenjun; Zhang, Xumu. Org. Lett. 2012, 14, 102.
11. Highly regioselective hydroaminomethylation of terminal olefins to linear amines using Rh complexes with a Tetrabi phosphorus ligand. Liu, Guodu; Huang, Kexuan; Cai, Chaoxian; Cao, Bonan; Chang, Mingxin; Wu, Wenjun; Zhang, Xumu. Chem. Eur. J. 2011, 17, 14559.
12. Ruthenium-catalyzed asymmetric hydrogenation of β-keto enamines: an efficient approach to chiral γ-amino alcohols. Geng, Huiling; Zhang, Xiaowei; Chang, Mingxin; Zhou, Le; Wu, Wenjun; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 3039.
13. Highly regioselective isomerization-hydroformylation of internal olefins catalyzed by Rhodium/tetraphosphine complexes. Cai, Chaoxian; Yu, Shichao; Liu, Guodu; Zhang, Xiaowei; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 2665.
14. A highly efficient and enantioselective access to tetrahydroisoquinoline alkaloids: asymmetric hydrogenation with an Iridium catalyst. Chang, Mingxin; Li, Wei; Zhang, Xumu. Angew. Chem. Int. Edit. 2011, 50, 10679.
15. Spiro-2,2'-bichroman-based bisoxazoline (SPANbox) ligands for Zn(II)-catalyzed enantioselective hydroxylation of β-keto esters and 1,3-diester. Li, Jie; Chen, Gang; Wang, Zheng; Zhang, Ruzhou; Zhang, Xumu; Ding, Kuiling. Chem. Sci. 2011, 2, 1141.
16. New synthetic strategy for high-enantiopurity N-protected α-amino ketones and their derivatives by asymmetric hydrogenation. Sun, Tian; Hou, Guohua; Ma, Miaofeng; Zhang, Xumu. Adv. Synth. Catal. 2011, 353, 253.
17. Enantioselective synthesis of optically pure β-amino ketones and γ -aryl amines by Rh-catalyzed asymmetric hydrogenation. Geng, Huiling; Huang, Kexuan; Sun, Tian; Li, Wei; Zhang, Xiaowei; Zhou, Le; Wu, Wenjun; Zhang, Xumu. J. Org. Chem. 2011, 76, 332.
18. Synthesis of enamides via Cu(I)-catalyzed reductive acylation of ketoximes with NaHSO3. Guan, Zheng-Hui; Zhang, Zhi-Yuan; Ren, Zhi-Hui; Wang, Yao-Yu; Zhang, Xumu. J. Org. Chem. 2011, 76, 339.
发明专利：
1. “New Chiral Ferrocene Phosphines and Their Applications for Asymmetric Catalytic Reactions” X. Zhang, US patent 09/781,083, filed February 9, 2001 and PCT/US01/044.
2. "3,3'-Substituted Chiral Biaryl Phosphines and Phosphintes for Asymmetric Catalytic Reactions ” X. Zhang, U. S. Patent, filed November 16, 2001 and PCT Application.
3. "New Transition Metal Catalyzed Reactions” A. Lei, X. Zhang, U. S. Provisional Patent, filed March 30, 2001.
4. “New Chiral Phospholanes for Asymmetric Catalysis” X. Zhang, US Patent filed November 6, 2001.
5. “P-chiral Phospholanes and Phosphocyclic compounds and their use in asymmetric catalytic reactions” W. Tang, X. Zhang, US provisional Patent, November 10, 2001.
6. “Asymmetric Reductive Amination of Ketones” X. Zhang, US Provisional Patent, filed October 25, 2002.
7. “P-chiral Phospholanes and Phosphocyclic compounds and their use in asymmetric catalytic reactions” W. Tang, X. Zhang, US Patent, November 10, 2002.
8. “New Chiral Oxazoline Ligands for Asymmetric Catalysis” D. Liu, X. Zhang, US Provisional Patent, December 17, 2003.
9. “Asymmetric Hydrogenation of Alpla-amino Carbonyl Compounds” X. Zhang, US Provisional Patent, January 10, 2004
10. “Preparation of chiral cyclic amino acids and derivatives” X. Zhang, W. Tang, US Patent 2004242889.
11. “P-Chiral Phospholanes and Phosphocyclic Compounds and their use in Asymmetric Catalytic Reactionss” X. Zhang, W. Tang, US patent 2004229846.
12. “Catalytic Asymmetric Reductive Amination of Ketones Via Transition Metal Complex Catalyst with Chiral Phosphine Ligands” X. Zhang, PCT, 2004, WO 2004058982.
13. “Preparation of Chiral Phosphorus Cyclic Compounds for Transition Metal-Catalyzed Asymmetric Reactions” X. Zhang, US patent, 2004, 2004072680.
14. “A preparation of aminoalcohols via asymmetric hydrogenation of beta-aminocarbonyl compounds” Zhang,
15. Xumu. US 2005159604 A1 20050721 Patent written in English. Application: US 2005-36157 20050114.
16. “New oxazoline ligands for asymmetric catalysis” Zhang, Xumu; Liu, Duan. U.S. Pat. Appl. Publ. (2005), 2005137403 A1 20050623.
17. “Chelating Tetraphosphorus Ligands with 1,1’-biphenyl backbone for transition Metal-catalyzed hydroformylation of Alkenes and Related Reactions” X. Zhang; Y. Yan, PCT Int. Appl. (2007) 2007078859. A2 20070712.
18. 新型三齿膦配体及其在线性氢甲酰化及类似反应中的应用（P）. 张绪穆，陈才友. 中国发明专利，CN102875599. 2013-01-16.
